CobaltMaghrebV1, France, Analysis, bibRecord, 000058

(2,3,7,8,12,13,17,18-Octaethylporphyrinato-κ4N)cobalt(II)–2-nitrobenzaldehyde (1/2)

Identifieur interne : 000058 ( France/Analysis ); précédent : 000057; suivant : 000059

(2,3,7,8,12,13,17,18-Octaethylporphyrinato-κ4N)cobalt(II)–2-nitrobenzaldehyde (1/2)

Auteurs : Anissa Mansour [Tunisie] ; Jean-Claude Daran [France] ; Habib Nasri [Tunisie]

Source :

Acta Crystallographica Section E: Structure Reports Online [ 1600-5368 ] ; 2012.

RBID : PMC:3435623

Abstract

The asymmetric unit of the title compound, [Co(C₃₆H₄₄N₄)]·2C₇H₅NO₃, is composed of one half of the complex, arranged about an inversion center, and a complete 2-nitrobenzaldehyde (NBA) molecule. The structure consists of columns that contain interleaved molecules of NBA and [Co^II(OEP)] (OEP is 2,3,7,8,12,13,17,18-octaethylporphyrin), which are stacked along the a axis. The Co^II atom is involved in a π interaction with the ring of the NBA molecule with a centroid–metal distance of 3.508 (6) Å. There is an intramolecular C—H⋯O hydrogen bond in the NBA molecule.

Url:

http://www.ncbi.nlm.nih.gov/pmc/articles/PMC3435623

DOI: 10.1107/S1600536812036112
PubMed: 22969496
PubMed Central: 3435623

Affiliations:

France, Tunisie

Links to Exploration step

PMC:3435623

Le document en format XML

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Serveur d'exploration sur le cobalt au Maghreb

(2,3,7,8,12,13,17,18-Octaethylporphyrinato-κ4N)cobalt(II)–2-nitrobenzaldehyde (1/2)

(2,3,7,8,12,13,17,18-Octaethylporphyrinato-κ4N)cobalt(II)–2-nitrobenzaldehyde (1/2)

Source :

Abstract

Links toward previous steps (curation, corpus...)

Links to Exploration step

Le document en format XML

Pour manipuler ce document sous Unix (Dilib)

Pour mettre un lien sur cette page dans le réseau Wicri

Pour générer des pages wiki

	Serveur d'exploration sur le cobalt au Maghreb
	Attention, ce site est en cours de développement ! Attention, site généré par des moyens informatiques à partir de corpus bruts. Les informations ne sont donc pas validées.

Serveur d'exploration sur le cobalt au Maghreb

(2,3,7,8,12,13,17,18-Octa­ethyl­porphyrinato-κ4N)cobalt(II)–2-nitro­benzaldehyde (1/2)

(2,3,7,8,12,13,17,18-Octa­ethyl­porphyrinato-κ4N)cobalt(II)–2-nitro­benzaldehyde (1/2)

Source :

Abstract

Links toward previous steps (curation, corpus...)

Links to Exploration step

Le document en format XML

Pour manipuler ce document sous Unix (Dilib)

Pour mettre un lien sur cette page dans le réseau Wicri

Pour générer des pages wiki

(2,3,7,8,12,13,17,18-Octaethylporphyrinato-κ4N)cobalt(II)–2-nitrobenzaldehyde (1/2)

(2,3,7,8,12,13,17,18-Octaethylporphyrinato-κ4N)cobalt(II)–2-nitrobenzaldehyde (1/2)